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Enhanced photovoltaic characteristics of solar cells based on n-type triphenodioxazine derivative
Authors:Fen Qiao  Yi Xiao  Ji quan Zhang
Affiliation:a School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024, PR China
b The State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, PR China
c Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, PR China
Abstract:
Polymer solar cells based on poly (2-methoxy-5-(2′-ethyl-hexyloxy)-1, 4-phenylene vinylene) (MEH-PPV):1-(3-methoxycarbonyl)-propyl-1-1-phenyl-(6,6)C61(PCBM):3, 10-di(trifluoromethane) triphenodioxazine (TFTD) was fabricated using spin coating technology. The absorption spectra of MEH-PPV: PCBM: TFTD film coated from chlorobenzene solution was broadened and showed higher intensity compared with that of the pure MEH-PPV. The TFTD acting as electron acceptors in combination with PCBM induced the photoluminescence (PL) quenching of MEH-PPV, which were associated with the photoinduced charge transfer characteristics of composite film. Further, a photovoltaic conversion efficiency up to 1.03% under 16.7 mW/cm2 white light illumination was achieved in the MEH-PPV: PCBM: TFTD system.
Keywords:Polymer   Absorption spectra   Photoluminescence   Photovoltaics
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