| 微波辐射合成1-甲基-2-硝基亚胺基-5-正丙基-六氢化-1，3，5-三嗪 |
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| 引用本文： | 王党生,鲍猛,杨秀利,韩斌.微波辐射合成1-甲基-2-硝基亚胺基-5-正丙基-六氢化-1，3，5-三嗪[J].精细化工中间体,2009,39(2):26-27. |
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| 作者姓名： | 王党生 鲍猛 杨秀利 韩斌 |
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| 作者单位： | 济南大学,化学化工学院,山东,济南,250022 |
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| 摘 要： | 在微波辐射下，以甲基硝基胍、正丙胺及甲醛为原料合成1-甲基-5-正丙基-2-硝基亚胺基-六氢化-1，3，5-三嗪。对产物进行红外分析和熔点测定。用正交实验方法对反应温度、反应时间及反应物用量等影响因素进行考察。得到合成反应的优化反应条件：n（甲基硝基胍）：n（正丙胺）：n（甲醛）=3：7．5：9．5，反应温度50℃，反应时间4min。收率达91．2％。
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| 关 键 词： | 1-甲基2-硝基亚胺基-5-正丙基-六氢化-1 3 5-三嗪 合成 微波辐射 |
Synthesis of 1-Methyl-2-nitroimino-5-n-propyl-1,3,5-triazacyclohexane under Microwave Irradiation |
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| WANG Dang-sheng,BAO Meng,YANG Xiu-li,HAN Bing.Synthesis of 1-Methyl-2-nitroimino-5-n-propyl-1,3,5-triazacyclohexane under Microwave Irradiation[J].Fine Chemical Intermediates,2009,39(2):26-27. |
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| Authors: | WANG Dang-sheng BAO Meng YANG Xiu-li HAN Bing |
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| Affiliation: | School of Chemistry and Chemical Engineering;University of Ji'nan;Ji'nan 250022;China |
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| Abstract: | 1-Methyl-2-nitroimino-5-n-propyl-1,3,5-triazacyclohexane was synthesized from methyl nitroguanidine,n-propylamine and formaldehyde under microwave irradiation.The products were identified by means of melting point and IR spectra.Based on the results from orthogonal design experiments,optimal conditions were obtained as:reaction temperature 50℃,irradiation time 4 min,the ratio of raw materials n(methyl nitroguanidine):n(n-propylamine):n(formaldehyde)=3:7.5:9.5.The overall yield was 91.2 %. |
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| Keywords: | 1-methyl-2-nitroimino-5-n-propyl-1 3 5-triazacyclohexane synthesis microwave irradiation |
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