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高压酸浸镍钼矿提取钼和镍
引用本文:王私富,魏昶,邓志敢,李存兄,李兴彬,吴钧,王明双,张帆.高压酸浸镍钼矿提取钼和镍[J].中国有色金属学会会刊,2013,23(10):3083-3088.
作者姓名:王私富  魏昶  邓志敢  李存兄  李兴彬  吴钧  王明双  张帆
作者单位:1. 昆明理工大学 冶金与能源工程学院,昆明 650093; 云南华联锌铟股份有限公司,文山 663701
2. 昆明理工大学 冶金与能源工程学院,昆明,650093
基金项目:50874053) supported by the National Natural Science Foundation of China,Project (2009AA06Z106) supported by Hi-Tech Research and Development Program of China,Project (20115314110001) supported by Doctoral Fund of Ministry of Education of China
摘    要:研究一项针对镍钼矿用高压酸浸的方法回收镍和钼的全湿法工艺。采用该工艺避免了传统上艺焙烧镍钼矿(15%~25%s)带来的人量S02和As2O3排放,减小了对环境的污染;与现有的湿法碱浸回收钼工艺相比,本工艺存酸浸过程中回收了儿乎全部的镍和人部分的钼。在氧压环境下,几乎全部的镍和大部分的钼都进入溶液,少部分的钼留在酸浸渣中,睃浸渣进一步用碱(NaOH)浸出。在最佳的实验条件下,97%的镍和96%的钼分别被浸出。

关 键 词:镍钼矿  高压酸浸  常压碱浸    
收稿时间:4 September 2012

Extraction of molybdenum and nickel from Ni-Mo ore by pressure acid leaching
Si-fu WANG,Chang WEI,Zhi-gan DENG,Cun-xiong LI,Xin-bing LI,Jun WU,Ming-shuang WANG,Fan ZHANG.Extraction of molybdenum and nickel from Ni-Mo ore by pressure acid leaching[J].Transactions of Nonferrous Metals Society of China,2013,23(10):3083-3088.
Authors:Si-fu WANG  Chang WEI  Zhi-gan DENG  Cun-xiong LI  Xin-bing LI  Jun WU  Ming-shuang WANG  Fan ZHANG
Affiliation:1. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2. Yunnan Hualian Zinc and Indium Limited by Share Ltd., Wenshan 663701, China Received 4 September 2012; accepted 26 April 2013)
Abstract:A direct hydrometallurgical route for nickel and molybdenum extraction from a nickel-molybdenum (Ni-Mo) ore using pressure acid leaching was studied. The nickel and molybdenum were extracted by acid leaching under oxygen pressure. Compared with traditional roasting methods, this hydrometallurgical method eliminates SO2 and As203 emission (the Ni-Mo ore containing 15%-25% S). Compared with existing alkali leaching recovery of molybdenum process, almost all the nickel and considerable molybdenum were extracted in the acid leaching process. Under oxygen pressure conditions, almost all the nickel and a substantial part of the molybdenum were dissolved into the acid leaching liquor and the other part of the molybdenum was left in the acid leach residue. The acid leach residue was further leached under alkaline (NaOH) conditions. Under optimal experimental conditions, the extraction rates nickel and molybdenum reached 97% and 96%, respectively.
Keywords:nickel-molybdenum ore  pressure leaching  alkaline leaching  nickel  molybdenum
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