| 新型CuO/ZnO催化剂的制备及其在水煤气变换反应中的应用 |
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| 引用本文： | 陈崇启,詹瑛瑛,林性贻,郑起.新型CuO/ZnO催化剂的制备及其在水煤气变换反应中的应用[J].工业催化,2008,16(4):55-58. |
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| 作者姓名： | 陈崇启 詹瑛瑛 林性贻 郑起 |
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| 作者单位： | 福州大学化肥催化剂国家工程研究中心，福建 福州 350002 |
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| 基金项目： | 国家自然科学基金
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福建省科技攻关项目 |
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| 摘 要： | 首次采用沉积沉淀法，以Cu（OH）2为前驱体制备不同CuO负载质量分数的CuO/ZnO水煤气变换（WGS）催化剂，并运用XRD、N2物理吸附和TPR等方法对催化剂进行结构表征。结果表明，活性组分CuO在载体ZnO表面的分散程度、颗粒大小及CuO和ZnO之间相互作用对催化剂的活性均有影响。CuO的适宜负载质量分数为20％，所得CuO/ZnO催化剂样品WGS反应活性较好，在350 ℃，CO转化率可达95.5％。
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| 关 键 词： | 催化剂工程 CuO/ZnO催化剂 水煤气变换 沉积沉淀法 |
| 文章编号： | 1008-1143(2008)04-0055-04 |
| 修稿时间： | 2007年11月20 |
Preparation of a new CuO/ZnO catalyst and its application in water-gas shift reaction |
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| CHEN Chongqi,ZHAN Yingying,LIN Xingyi,ZHENG Qi.Preparation of a new CuO/ZnO catalyst and its application in water-gas shift reaction[J].Industrial Catalysis,2008,16(4):55-58. |
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| Authors: | CHEN Chongqi ZHAN Yingying LIN Xingyi ZHENG Qi |
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| Affiliation: | National Engineering Research Center of Chemical Fertilizer Catalyst，;Fuzhou University, Fuzhou 350002, Fujian，China |
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| Abstract: | CuO/ZnO catalysts with different CuO content were prepared by deposition precipitation method for water gas shift reaction, using Cu(OH)2 as the precursor of CuO. The as prepared catalysts were characterized by N2 physisorption, TPR and XRD. The results showed that catalytic activity of the as prepared catalysts was influenced by the dispersion and particles size of CuO as well as the interaction between CuO and ZnO. 20wt%CuO/ZnO catalyst exhibited superior catalytic activity for water gas shift reaction, with CO conversion of 95.5% at 350 ℃. |
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| Keywords: | CuO/ZnO catalyst water gas shift reaction deposition precipitation method catalyst engineering |
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