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Tailoring the structural,electrical, and optical features of Erbium(III)-Tris(8-hydroxyquinolinato) nanostructured films for optical applications: effect of film thickness
Authors:Alsharari  Abdulrhman M  Qashou  Saleem I  Hamdalla  Taymour A  Alatawi  Naifa S  Alsharif  Marwah Ahmed  Alam  Khan  Mihaina  Ibrahim A M  Qaessy  Hajeer  Yahia  I S  Darwish  A A A
Affiliation:1.Department of Physics, Faculty of Science, University of Tabuk, Tabuk, 71491, Kingdom of Saudi Arabia
;2.Nanotechnology Research Unit, Faculty of Science, University of Tabuk, Tabuk, 71491, Kingdom of Saudi Arabia
;3.Department of Physics, Faculty of Science, Zarqa University, Zarqa, 13132, Jordan
;4.Department of Physics, Faculty of Science, University of Alexandria, Alexandria, Egypt
;5.Department of Physics, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Kingdom of Saudi Arabia
;6.Department of Chemistry, Faculty of Science, University of Tabuk, Tabuk, Kingdom of Saudi Arabia
;7.ME-Physics Master Program, Physics Department, Faculty of Science, University of Tabuk, Tabuk, Kingdom of Saudi Arabia
;8.Department of Physics, Faculty of Education, Ain Shams University, Roxy 11757, Cairo, Egypt
;9.Research Center for Advanced Materials Science (RCAMS), Department of Physics, Faculty of Science, King Khalid University, and Advanced Functional Materials & Optoelectronic Laboratory (AFMOL), King Khalid University, P.O. Box 9004, Abha, Kingdom of Saudi Arabia
;10.Department of Physics, Faculty of Education et al-Mahweet, Sana’a University, Al-Mahweet, Yemen
;
Abstract:

This paper elaborates on the thickness-dependent structural, optical, and electrical properties of Erbium(III)-Tris-8-hydroxyquinolinato (ErQ3) films. The surface morphology reveals the grains that consolidate to make denser films with increasing film thickness. The ErQ3 grain sizes increased from 80 to 187 nm as the thickness increased from 80 to 190 nm. From XRD analysis, the ErQ3 films are partially crystallized with only one peak at 2θ?=?9.80° and a plateau in the range of 20–40°. Electrical measurement of ErQ3 films showed that the electrical conductivity had a strong dependence on film thickness. Transmittance and reflectance measurements showed that the films exhibited a 2.60 eV bandgap, and it does not depend on the thickness of the film. Also, the dispersion of the refractive index was analyzed to determine the essential parameters. The nonlinear optical parameters such as nonlinear refractive index and third-order nonlinear optical susceptibility were calculated by Miller's principles.

Keywords:
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