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Copper(II) removal from aqueous solutions by fly ash
Authors:KK Panday  Gur Prasad  VN Singh
Affiliation:Applied Chemistry, Institute of Technology, Banaras Hindu University, Varanasi-221005, India
Abstract:The removal of Cu(II) by adsorption on fly ash has been found to be concentration, pH and temperature dependent. The kinetics of adsorption indicates the process to be diffusion controlled. The Langmuir constants have been calculated at different temperatures, and the adsorption has been found to be endothermic (ΔH = 15.652 kcal mol?1). The maximum removal is observed at pH 8.0, and variation in adsorption with pH has been explained on the basis of surface ionisation and complexation.
Keywords:fly ash  Cu(II)  adsorption dynamics  mass transfer coefficient  pore diffusion  Langmuir isotherm  surface ionisation  complexation
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