Effect of titanium substitution on the structure and properties of Fe3Al-based intermetallic alloys

Substitutions (0–16 at%) of titanium for iron in Fe₃Al-based alloys rapidly solidified by chill-block melt-spinning stabilize the D0₃ and B2 ordered structures. Rapid solidification results in total suppression of D0₃ order in binary alloys, whereas alloys containing titanium have D0₃ structure. D0₃ and B2 antiphase domain size, lattice parameter and hardness increase with increasing titanium content of the alloy. The deformation mode changes from single (unit) bcc dislocation in binary alloys to two-fold superdislocation configuration in D0₃Fe₃Al-Ti alloys. Mechanical antiphase boundaries are generated by the movement of these imperfect configurations. All the alloys exhibited cleavage tensile failure. The mechanical properties are correlated with the observed structural changes.