| 微乳液法合成旋光性共聚物 |
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| 引用本文： | 王国祥,刘朋生.微乳液法合成旋光性共聚物[J].中国矿业大学学报,2006,35(1):130-134. |
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| 作者姓名： | 王国祥 刘朋生 |
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| 作者单位： | 1. 湘潭大学,化学学院,湖南,湘潭,411105;湖南理工学院,化学化工系,湖南,岳阳,414000
2. 湘潭大学,化学学院,湖南,湘潭,411105 |
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| 摘 要： | 以过硫酸钾（KPS）为引发剂、以十二烷基硫酸钠（SDS）和正戊醇（PTL）为复合乳化剂，对N-马来酰基-L-氨基丙酸（AMI）和苯乙烯（St）进行了微乳液共聚合实验并制得了具有光学活性共聚物．考察了单体配比、引发剂浓度、温度对反应速率（R，）的影响．用元素分析法确定了共聚物内氮含量与单体组成比之间的关系，进而计算出两单体的竞聚率，并计算出相应的Q、e值：r1=0．05，r2=0．10，Q1=1．59，e1=1．50．计算了共聚合反应活化能Ea值：Ea=82．86kJ／mol．讨论了共聚物组成及二元序列、平均序列长度、温度对共聚物旋光度的影响．
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| 关 键 词： | N-马来酰基-L-丙氨酸 苯乙烯 微乳液 旋光性 |
| 文章编号： | 1000-1964(2006)01-0130-05 |
| 收稿时间： | 02 20 2005 12:00AM |
| 修稿时间： | 2005年2月20日 |
Synthesis of Optically Active Polymers in Microemulsion Process |
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| WANG Guo-xiang,LIU Peng-sheng.Synthesis of Optically Active Polymers in Microemulsion Process[J].Journal of China University of Mining & Technology,2006,35(1):130-134. |
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| Authors: | WANG Guo-xiang LIU Peng-sheng |
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| Affiliation: | 1. College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105, China ; 2. College of Chemistry of Hunan institute of Technology, Yueyang, Hunan 414000, China |
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| Abstract: | Chiral N-maleoyl-L-alanine(AMI) and styrene(St) were copolymerized in the oil-water microemulsion by using potassium persulfate(KPS) as initiator,sodium dodecyl sulfate(SDS) as anionic emulsifier,and pentanol as consurfactant.The resulting polymers are optically active.The monomer reactivity ratios(r_1,r_2),Alfrey-Price Q,and e values are calculated, which are r_1=0.05,r_2=0.10,Q_1=1.59,and e_1=1.50,respectively.The effects of initiator concentration,molar fraction of monomer in feed and reaction temperature on the polymerization rate(R_p) have been investigated.The overall energy of activation(E_a) is 82.86 kJ/mol. |
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| Keywords: | N-maleoyl-L-alanine styrene microemulsion Optically active |
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