Bias in Filter-Based Aerosol Light Absorption Measurements Due to Organic Aerosol Loading: Evidence from Laboratory Measurements |
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| Authors: | Christopher D. Cappa Daniel A. Lack James B. Burkholder A. R. Ravishankara |
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| Affiliation: | 1. Chemical Science Division, NOAA Earth System Research Laboratory , Boulder, Colorado, USA;2. Cooperative Institute for Research in Environmental Science, University of Colorado , Boulder, Colorado, USA;3. Department of Civil and Environmental Engineering , University of California , Davis, California, USA;4. Cooperative Institute for Research in Environmental Science, University of Colorado , Boulder, Colorado, USA;5. Chemical Science Division, NOAA Earth System Research Laboratory , Boulder, Colorado, USA;6. Department of Chemistry and Biochemistry , University of Colorado , Boulder, Colorado, USA |
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| Abstract: | ![]()
Light absorption by soot or nigrosin dye aerosol particles were measured in the laboratory using a particle soot absorption photometer (PSAP) and a photo-acoustic spectrometer (PAS) to assess the influence of non-absorbing organic aerosol (OA) on the PSAP measurements. For the PSAP, particle light absorption is measured after collection on a filter, whereas for the PAS light absorption is measured while the particles remain suspended in the gas phase. OA was generated from the reaction of α -pinene with ozone. It was observed that the presence of this OA in an external mixture of absorbing aerosol and OA can cause an increase in the light absorption measured by the PSAP, relative to that measured by the PAS, by more than a factor of two. This enhancement in the PSAP absorption was found to increase as the amount of OA increased relative to the absorbing compound. Additionally, experiments where absorbing aerosol was deposited on a PSAP filter prior to addition of OA demonstrated that the non-absorbing OA can actually appear as if it were absorbing, with measured single scattering albedo values as low as 0.92. These results indicate that filter-based measurement techniques may significantly overestimate light absorption by aerosols in the atmosphere under conditions where the organic loading is large, with consequent implications for understanding and calculating the Earth's radiation budget. These laboratory experiments aid in the interpretation of results from a recent field study, discussed in a companion article (Lack et al. 2008 Lack, D. A., Cappa, C. D., Baynard, T., Massoli, P., Covert, D. S., Sierau, B., Bates, T. S., Quinn, P. K., Lovejoy, E. R. and Ravishankara, A. R. 2008. Bias in Filter-Based Aerosol Absorption Measurements Due to Organic Aerosol Loading: Evidence from Ambient Measurements. Aerosol Sci. and Technol., 42: 1033–1041. [Taylor & Francis Online], [Web of Science ®] , [Google Scholar]). |
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