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高硅含量硅丙乳液的性能研究
引用本文:辛转红,张爱黎. 高硅含量硅丙乳液的性能研究[J]. 沈阳理工大学学报, 2010, 29(4): 63-67
作者姓名:辛转红  张爱黎
作者单位:沈阳理工大学环境与化学工程学院,辽宁沈阳110159
摘    要:
采用单体滴加法制备了高硅含量的硅丙乳液.用红外光谱对乳液涂膜性能进行了分析和表征.研究了乳化剂的配比和用量,电解质的用量以及油水比对乳液性能的影响.研究表明:非离子型乳化剂OP-10和阴离子型乳化剂十二烷基磺酸钠配比为2/1,用量为2.0%,电解质用量为0.5%,油水比为0.6,合成硅含量占丙烯酸酯单体总量40%的硅丙乳液,其各项性能符合国家标准GB/T20623-2006.

关 键 词:高硅含量  硅丙乳液  乳液聚合

Performance Research of Silicon-Acrylate Emulsion of High Organosiloxane Content
XIN Zhuan-hong,ZHANG Ai-li. Performance Research of Silicon-Acrylate Emulsion of High Organosiloxane Content[J]. Transactions of Shenyang Ligong University, 2010, 29(4): 63-67
Authors:XIN Zhuan-hong  ZHANG Ai-li
Affiliation:(Shenyang Ligong University,Shenyang 110159,China)
Abstract:
Silicon-acrylate emulsion of high organosiloxane content was synthesized by monomer drip method.The property of its film is analysed by IR.The emulsifier content and rate,electrolytical dosage and grease-water proportion were investigated.It was found that Silicon-Acrylate Emulsion of 40% Organosiloxane content has excellent comprehensive performance in accordance with GB/T20623-2006 when the appropritate rate of OP-10 and SLS is 2:1,the right amount of emulsifier is 2.0% of the monomer's,the electrolytical capacity is 0.5% and grease-water proportion is 0.6.
Keywords:high organosiloxane content  silicon-acrylate emulsion  emulsion polymerization
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