Abstract: | Barium hexaferrite BaFe12O19 (BHF) ceramic was synthesized by chemical route on sintering at 1050 °C for 12 h. The synthesized material was characterized by XRD, SEM, AFM and TEM analysis. Metal oxide stretching frequencies corresponding to Fe-O, Ba-O, and Fe-O-Fe bands are confirmed by FTIR studies. The hexagonal nature of the BHF ceramic was confirmed by TEM analysis and Rietveld refinement with space group P63/mmc. The particle size observed by TEM is 175 nm. The root means square and average roughness were found to be 61.048 nm and 44.025 nm respectively. The M-T and M-H hysteresis loop indicates temperature dependent ferromagnetic behavior of BHF ceramic. The temperature and frequency dependent dielectric properties were explained by Maxwell-Wagner theory. The value of dielectric constant (ε′) for BHF ceramic was found to be 22× 103 at 100 Hz and 483 K. |