| 1,4-丁二醇脱氢环化制γ-丁内酯的动力学研究 |
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| 引用本文： | 林衍华,骆有寿.1,4-丁二醇脱氢环化制γ-丁内酯的动力学研究[J].精细石油化工,1995(4). |
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| 作者姓名： | 林衍华 骆有寿 |
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| 作者单位： | 浙江大学二次资源化工国家专业实验室 杭州310027 |
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| 摘 要： | 研究了1,4-丁二醇在Cu-ZnO-Al_2O_3;催化剂上液相脱氢环化制γ-丁内酯反应过程,并探讨反应机理.对实验数据进行拟合,得到该反应速率方程.
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| 关 键 词： | 动力学 脱氢 环化 γ-丁内酯 1 4-丁二醇 |
STUDY ON KINETIC FOR PREPARING γ-BUTYROLACTONE FROM 1,4-BUTANEDIOL |
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| Lin Yanhua and Luo YoushouKey Program Laboratory for Second Resoures Chemical Engineering and Industry,ZheJiang University.STUDY ON KINETIC FOR PREPARING γ-BUTYROLACTONE FROM 1,4-BUTANEDIOL[J].Speciality Petrochemicals,1995(4). |
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| Authors: | Lin Yanhua and Luo YoushouKey Program Laboratory for Second Resoures Chemical Engineering and Industry ZheJiang University |
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| Abstract: | γ-Butyrolactone is an important finechemical intermediate. The chemical reaction process of the liquid phase dehydrocyclization reaction of 1,4-butanediol over a Cu-ZnO-Al2O3 catalyst for preparing γ-butyrolac-tone was studied and the reaction mechanism was discussed. According to the experimental data, the rate equation was deduced. |
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| Keywords: | Kinetic Dehydrogeuation Cyclization γ-Butyrolactone 1 4-Butanediol |
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