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Direct electrochemical reduction of indigo
Authors:Albert Roessler  David CrettenandOtmar Dossenbach  Walter MartePaul Rys
Affiliation:a Laboratory of Chemical Engineering and Technology, Swiss Federal Institute of Technology (ETH), CH-8093 Zurich, Switzerland
b Tex-A-Tec AG, Anlagen und Prozesstechnik, Industriegebiet Färch, CH-9630 Wattwil, Switzerland
Abstract:Reducing agents required in the dyeing process for vat and sulfur dyes cannot be recycled, and lead to problematic waste products. Therefore, modern economical and ecological requirements are not fulfilled. The application of direct electrochemical reduction of indigo as a novel route has been investigated by spectrophotometric and voltammetric experiments in laboratory cells. Experiments yield information about the reaction mechanism and the kinetics, and they show the possibility of this new route for production of water-soluble indigo, which offers tremendous environmental benefits.
Keywords:Electrochemical reduction   Indigo   Indigo radical   Leuco-indigo   Vat dyes
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