| 介孔分子筛负载杂多酸催化剂催化合成邻苯二甲酸二辛酯 |
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| 引用本文： | 陆勇.介孔分子筛负载杂多酸催化剂催化合成邻苯二甲酸二辛酯[J].化工时刊,2007,21(5):20-21. |
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| 作者姓名： | 陆勇 |
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| 作者单位： | 南京第十四研究所,江苏,南京,210013 |
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| 摘 要： | 采用介孔分子筛负载杂多酸为催化剂,在釜式反应器内对苯酐和正辛醇的酯化反应进行了研究,考察了催化剂的活性、选择性和稳定性,结果表明,在组成适宜的催化剂和适当的反应条件下,苯酐转化率可达98%,DOP选择性可达100%,且催化剂可重复多次使用。
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| 关 键 词： | 介孔分子筛 杂多酸 催化剂 酯化反应 |
| 收稿时间： | 2007-03-30 |
| 修稿时间： | 2007年3月30日 |
Synthesis of DOP Catalyzed by Mesoporous Molecular Sieves Loaded with Heteropolyacid |
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| Lu Yong.Synthesis of DOP Catalyzed by Mesoporous Molecular Sieves Loaded with Heteropolyacid[J].Chemical Industry Times,2007,21(5):20-21. |
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| Authors: | Lu Yong |
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| Affiliation: | Nanjing Research Institute of Electronic Technology, Jiangsu Nanjing 210013 |
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| Abstract: | The esterification of anhydride with n-octanol over mesoporous molecular sieves loaded with heteropolyacid was studied.The effects of catalytic activity,selectivity and stability were investigated.The experimental results show that the conversion of anhydride can reach 98% and the selectivity of DOP is 100% under optimum.Moreover the catalyst can be used repetitively. |
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| Keywords: | mesoporous molecular sievesheteropolyacid esterification |
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