| 复合氧化剂界面聚合制备导电聚苯胺纳米纤维 |
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| 引用本文： | 马超云,李玲,范焕新,房辉. 复合氧化剂界面聚合制备导电聚苯胺纳米纤维[J]. 电子元件与材料, 2012, 31(7): 59-62. DOI: 10.3969/j.issn.1001-2028.2012.07.017 |
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| 作者姓名： | 马超云 李玲 范焕新 房辉 |
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| 作者单位： | 1.暨南大学物理系,广东广州,510632;2.暨南大学物理系,广东广州,510632;3.暨南大学物理系,广东广州,510632;4.暨南大学物理系,广东广州,510632 |
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| 摘 要： | 利用盐酸和四氧化碳的水/油两相界面,以过硫酸铵(APS)和重铬酸钾为复合氧化剂,首次采用复合氧化剂界面聚合法制备纳米纤维状聚苯胺( PANI).研究了复合氧化剂配比对掺杂态聚苯胺电导率和产率的影响.结果表明,在室温下,当采用摩尔分数90％APS和10％重铬酸钾复合氧化剂时,产物形貌呈网状纤维状,直径为50～80 nm,长度为500nm至几微来不等,电导率和产率分别为1.89 S/cm,49.03％.
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| 关 键 词： | 聚苯胺 复合氧化剂 界面聚合 纳米纤维 |
Conductive polyaniline nanofibers synthesized by interfacial polymerization with compound oxidant |
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| MA Chaoyun , LI Ling , FAN Huanxin , FANG Hui. Conductive polyaniline nanofibers synthesized by interfacial polymerization with compound oxidant[J]. Electronic Components & Materials, 2012, 31(7): 59-62. DOI: 10.3969/j.issn.1001-2028.2012.07.017 |
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| Authors: | MA Chaoyun LI Ling FAN Huanxin FANG Hui |
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| Affiliation: | (Department of Physics,Jinan University,Guangzhou 510632,China) |
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| Abstract: | Utilizing the interface between HCl and CCl4,polyaniline(PANI) nanofibers were first prepared by interfacial polymerization with compound oxidant of(NH4)2S2O8 and K2Cr2O7.The influences of the(NH4)2S2O8/ K2Cr2O7 ratio on the PANI conductivity and yield were studied.The results show that with using the compound oxidant of 90%(mole fraction)(NH4)2S2O8 and 10% K2Cr2O7 at room temperature,the morphology of the sample is mesh nanofibers of which average diameter is 50-80 nm and the lengths range from 500 nm up to several micrometers,the conductivity and yield is 1.89 S/cm,49.03%,respectively. |
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| Keywords: | polyaniline compound oxidant interfacial polymerization nanofiber |
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