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乳酸掺杂聚苯胺/PP 树脂复合材料
引用本文:王元瑞,张易,彭南南,王刚,王树杰,刘威,陶玉仑.乳酸掺杂聚苯胺/PP 树脂复合材料[J].广州化工,2014(20):76-79.
作者姓名:王元瑞  张易  彭南南  王刚  王树杰  刘威  陶玉仑
作者单位:安徽理工大学,安徽 淮南,232001
基金项目:安徽省大学生创新创业项目(201310361118);安徽省理工大博士基金(11186)。
摘    要:乳液聚合法聚合乳酸掺杂聚苯胺。再使用开炼机混炼PP/聚苯胺,最后平板硫化仪得到永久抗静电聚苯胺/PP。研究发现,聚苯胺/PP复合材料的相容性好。通过掺杂,乳酸中解离出的H+与聚苯胺分子链上的N原子结合,使聚苯胺获得永久、稳定的导电性。结果证明,随着聚苯胺的添加量,体积电阻减小三个数量级,冲击强度、拉伸强度和硬度足以满足很多应用的要求。

关 键 词:乳酸掺杂聚苯胺  抗静电材料

The Composite of Lactic Acid Doped Polyaniline and Polypropylene Resin
WANG Yuan-rui,ZHANG Yi,PENG Nan-nan,WANG Gang,WANG Shu-jie,LIU Wei,TAO Yu-lun.The Composite of Lactic Acid Doped Polyaniline and Polypropylene Resin[J].GuangZhou Chemical Industry and Technology,2014(20):76-79.
Authors:WANG Yuan-rui  ZHANG Yi  PENG Nan-nan  WANG Gang  WANG Shu-jie  LIU Wei  TAO Yu-lun
Affiliation:WANG Yuan-rui;ZHANG Yi;PENG Nan-nan;WANG Gang;WANG Shu-jie;LIU Wei;TAO Yu-lun;Anhui University of Science & Technology;
Abstract:Polyaniline doped with lactic acid was synthesized by emulsion polymerization.The antistatic polyaniline/PP composites were prepared after polyaniline was fully mixed in PP by the open smelting machine and the flat vulcanizing machine.The results indicated that the compatibility of polyaniline /PP composites was good.By doping , the H+which dissociated from lactic acid combined with the N atom of polyaniline molecular chains , so that the conductivity of polyaniline was lasting and stable.With the increase of polyaniline , volume resistance decreased three orders of magnitude , the impact strength , tensile strength and hardness was enough to meet the requirements of many applications.
Keywords:lactic acid doped polyaniline  polypropylene  antis tatic material
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