| Abstract: | Solvent extraction is an important process in the nuclear fuel cycle. Tributyl phosphate(TBP) diluted with dodecane is commonly used as a solvent for extracting heavy metals from nitric acid medium. Studies on hydrodynamics of a single drop, which is the smallest mass transfer entity, are required for better understanding of the complex mass transfer and phase separation phenomena that occur in extraction equipment. In this study, drop formation at nozzles is studied using 30% TBP-dodecane as the dispersed phase and dilute nitric acid as the quiescent continuous phase. Experiments are carried out to determine the drop diameter, jetting velocity, drop detachment height and drop detachment time for various dispersed phase velocities, nozzle diameters(1.91, 3.04, and 4.88 mm), and nitric acid concentrations(0.01, 1, 3 N). Drop formation is captured using high-speed imaging, which enables quantification of drop size, onset of jetting, drop detachment height, and drop detachment time. Experimental data are used to propose correlations for predicting drop diameter and minimum jetting velocity. The correlations are found to be very accurate with average absolute relative errors being 5.23 and 2.97%, respectively. |
