| 紫外辐照引发PF-g-SAN接枝共聚反应的研究 |
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| 引用本文： | 徐雅丽,应继儒,彭少贤,张莹.紫外辐照引发PF-g-SAN接枝共聚反应的研究[J].塑料助剂,2009(5):24-27. |
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| 作者姓名： | 徐雅丽 应继儒 彭少贤 张莹 |
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| 作者单位： | 湖北工业大学化学与环境工程学院,武汉,430068 |
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| 摘 要： | 以二苯甲酮（BP）为引发剂,通过紫外光辐照引发苯乙烯（St）、丙烯腈（AN）在纸浆纤维（PF）表面共聚,生成苯乙烯/丙烯腈共聚物（SAN）并接枝PF生成SAN接枝纸浆纤维（PE-g-SAN）,研究了引发剂BP浓度、St/AN质量比、辐照时间、反应温度对PF-g-SAN的接枝率和接枝效率的影响,用红外光谱仪和扫描电子电镜表征接枝产物,得出最佳反应条件为St/AN质量比2∶1,BP浓度2%,反应时间20 min,反应温度40℃。
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| 关 键 词： | 紫外辐照 纸浆纤维 苯乙烯-丙烯腈共聚物 接枝共聚 |
Study on Graft Polymerization for PF-g-SAN by UV Radiation |
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| Xu Ya-li,Ying Ji-ru,Peng Shao-xian,Zhang Ying.Study on Graft Polymerization for PF-g-SAN by UV Radiation[J].Plastic Additives,2009(5):24-27. |
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| Authors: | Xu Ya-li Ying Ji-ru Peng Shao-xian Zhang Ying |
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| Affiliation: | Xu Ya-li Ying Ji-ru Peng Shao-xian Zhang Ying(School of Chemical and Environmental Engineering,Hubei University of Technology,Wuhan,430068) |
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| Abstract: | Styrene（St） and acrylonitrile（AN） were copolmerized and then grafted on the surface of pulp fiber using benzophenone（BP）as a initiator under ultraviolet（UV） radiation.The effects of initator BP concentration,St/AN mass ratio,radiation time,and reaction temperature on grafting percentage and grafting efficiency of PF-g-SAN were studied.The grafting product was characterized by means of FTIR and SEM.The optimal reaction conditions are mass ratio of St/AN 2∶1,initator BP concentration of 2%,reaction time of 20 min,and reaction temperture of 40 ℃. |
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| Keywords: | ultraviolet radiation pulp fiber styrene-acrylonitrle copolymer graft polymerization |
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