| 取代四苯基卟啉的催化合成 |
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| 引用本文： | 雷裕武,郭灿城.取代四苯基卟啉的催化合成[J].化学试剂,1994,16(2):105-106. |
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| 作者姓名： | 雷裕武 郭灿城 |
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| 作者单位： | 湖南师范大学化学系 |
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| 摘 要： | 在无水ＡｌＣｌ３催化下由吡咯和取代苯甲醛直接综合制备了１２种取代四苯基卟啉ＴＸＰＰＨ２。研究表明，与目前文献报道的合成ＴＸＰＰＨ２的其他方法比较，该法具有产物的纯度好，操作简单，适应性广的优点。
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| 关 键 词： | 催化合成 卟啉 TXPPH2 三氯化铝 |
Catalytic synthesis of substituted tetraphenylporphyrins |
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| Lei Yuan,Guo Cancheng,Zeng Dezhong.Catalytic synthesis of substituted tetraphenylporphyrins[J].Chemical Reagents,1994,16(2):105-106. |
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| Authors: | Lei Yuan Guo Cancheng Zeng Dezhong |
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| Abstract: | Twelve kinds of substituted tetraphenylporphyrins (TXPPH_2)were synthesized by the direct condensation of pyrrole with substituted benzaldehyde by refluxing in DMF in the presence of AlCl_3.Compared with other methods in the literature,this method has the advantages of wider applicabilities,higher yields and better purity. |
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| Keywords: | anhydrous AlCl_3 catalytic synthesis porphyrin |
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