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| 表面修饰的纳米ZnO的加入对PEG结晶的影响 | |
| 引用本文： | 刘莹,石莹莹,孙光辉,程晔华,黄建平,汪宏杰.表面修饰的纳米ZnO的加入对PEG结晶的影响[J].河南化工,2010,27(15):34-38. |
| 作者姓名： | 刘莹 石莹莹 孙光辉 程晔华 黄建平 汪宏杰 |
| 作者单位： | 1. 开封龙宇化工有限公司,河南,开封,475200 2. 三门峡职业技术学院,河南,三门峡,472000 3. 河南省化工研究所有限责任公司,河南,郑州,450052 4. 开封龙宇化工有限公司,河南,开封,475200;南京工业大学,江苏,南京,210009 |
| 摘 要： | 在PEG溶液中加入纳米ZnO以及表面修饰的ZnO,观察纳米粒子对PEG结晶的影响。通过透射偏光显微镜进行观察,发现纳米ZnO的加入改变了PEG的结晶形貌,随着纳米粒子表面羧基含量的增加,结晶形貌按照树晶—大球晶—小球晶的规律变化。通过FTIR表明在热作用下纳米粒子表面的羧基会与PEG的端羟基发生酯化反应,使纳米ZnO可以稳定的存在于PEG溶液中,为球晶的形成提供了成核点。 |
| 关 键 词： | 纳米ZnO 聚乙二醇 结晶 |
Effect of Addtion of Nano-ZnO after Surface Modification to PEG Crystallization |
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| LIU Ying,SHI Ying-ying,SUN Guang-hui,CHENG Ye-hua,HUANG Jian-ping,WANG Hong-jie.Effect of Addtion of Nano-ZnO after Surface Modification to PEG Crystallization[J].Henan Chemical Industry,2010,27(15):34-38. | |
| Authors: | LIU Ying SHI Ying-ying SUN Guang-hui CHENG Ye-hua HUANG Jian-ping WANG Hong-jie |
| Affiliation: | LIU Ying , SHI Ying - ying, SUN Guang - hui, CHENG Ye - hua, HUANG Jian - ping, WANG Hong -jie3 (1. Kaifeng Longyu Chemical Co. , Ltd. Kaifeng 475200 , China ; 2. Sanmenxia Polytechnic, Sanmenxia 472000 , China ; 3. Henan Chemical Industry Research Institute, Zhengzhou 450052 , China ; 4. Nanjing University of Techndogy , Nanjing 210009 , China) |
| Abstract: | The nano- ZnO and ZnO after surface modification are added into PEG solution, the effect of nano - particles to PEG crystallization are observed. The result shows, the crystallization shape changes after adding nano - ZnO,with the increasing of carboxyl content on nano - particles surface, the crystallization shape changes on the low tree crystal,large spherulite and small spherulite. The FTIR measurements indicate that esterification reaction occurres between the hydroxyl - terminated of PEG and the carboxyl of nano -ZnO under thermal conditions, then, nano -ZnO can disperse in PEG solution stably, and provide nucleation point for the formation of spherulite. |
| Keywords: | nano- ZnO PEG crystallization |
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