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CaCO3/UP体系及CaCO3-GF/UP体系的流变特性及界面效应
引用本文:闻荻江.CaCO3/UP体系及CaCO3-GF/UP体系的流变特性及界面效应[J].复合材料学报,1986,3(3):8.
作者姓名:闻荻江
作者单位:武汉工业大学硅工系
摘    要:本文由钛酸酯处理的CaCO3/UP体系的流变特性,讨论了CaCO3在体系中的分散状态;探讨了CaCO3-GF/UP体系的流变特性及GF的分散结构,以及在CaCO3表面的偶联剂对CaCO3-GF/UP体系流变特性的界面效应。 

收稿时间:1985-12-27
修稿时间:1986-03-01

RHEOLOGICAL PROPERTIES AND SURFACE EFFECTS OF CaCO3/UP AND CaCO3-GLASS/UP SYSTEMS
Wen Dijiang.RHEOLOGICAL PROPERTIES AND SURFACE EFFECTS OF CaCO3/UP AND CaCO3-GLASS/UP SYSTEMS[J].Acta Materiae Compositae Sinica,1986,3(3):8.
Authors:Wen Dijiang
Affiliation:Department of Silicate Engineering, Wuhan Industrial University, Wuhan, China
Abstract:This paper discusses the rheological properties of CaCO3/UP and CaCO3-glass(UP systyms respectively in which CaCO3 has been treated by coupling agents.The results indicate that the dispersion state of CaCO3 in CaCO3/UP system will change from a single particle state to aaccumulated group structure gradually,accompanying by the increase of CaCO3 content.The rheological properties of the system that consists of accumulated group structures can be shown by the formula In ηγ=9.23φ/(1-2.0φ).As to CaCO3-glass/UP system,its rheological properties ate obviousiy affected by glass fibres,and there exists a loose structure that is mechanically formed between glass fibres.Casson equation can be used to characcterize this system so long as glass fibre content is small,and ý is less than 100 s-1.It is found that the different molecular structures on coupling agents and their different combination forms on the surface of CaCos will bring about different surface effects on the rheological properties of the systems.
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