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高浓度H2O-NH3-CO2体系汽液平衡计算
引用本文:魏顺安,张红晶. 高浓度H2O-NH3-CO2体系汽液平衡计算[J]. 中国化学工程学报, 2004, 12(1)
作者姓名:魏顺安  张红晶
摘    要:



Calculation of H2O-NH3-CO2 Vapor Liquid Equilibria at High Concentration Conditions
WEI Shun''an,ZHANG Hongjing. Calculation of H2O-NH3-CO2 Vapor Liquid Equilibria at High Concentration Conditions[J]. Chinese Journal of Chemical Engineering, 2004, 12(1)
Authors:WEI Shun''an  ZHANG Hongjing
Affiliation:Chemistry and Chemical Engineering Institute, Chongqing University, Chongqing 400044, China;Chemistry and Chemical Engineering Institute, Chongqing University, Chongqing 400044, China
Abstract:
A vapor liquid equilibrium model and its related interactive energy parameters based on UNIQUAC model for the H2O-NH3-CO2 system without solid phase at the conditions of temperature from 30℃ to 90℃,pressure from 0.1 MPa to 0.4 MPa, and the maximum NH3 mass fraction up to 0.4 are provided. This model agrees with experimental data well (average relative error < 1%) and is useful for analysis of industrial urea production.
Keywords:H2O-NH3-CO2 system  vapor liquid equilibrium  high concentration  thermodynamic model
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