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TPI结晶性对CV体系硫化SBR/TPI并用胶性能的影响
引用本文:张志广,张俊平,杜爱华.TPI结晶性对CV体系硫化SBR/TPI并用胶性能的影响[J].弹性体,2011,21(3):1-5.
作者姓名:张志广  张俊平  杜爱华
作者单位:青岛科技大学橡塑材料与工程教育部重点实验室,山东青岛,266042
基金项目:山东省教育厅资助项目(BS2009CL024); 国家自然科学基金资助项目(51073085)
摘    要:研究了反式-1,4-聚异戊二烯(TPI)结晶性对传统硫磺硫化(CV)体系硫化丁苯橡胶(SBR)/TPI并用胶硫化特性及物理性能的影响。结果表明,增大TPI的并用量,能够提高SBR/TPI并用胶的交联密度和硫化速度,延长焦烧时间;TPI冷冻结晶对SBR/TPI并用硫化胶的拉伸性能影响不大,拉伸诱导结晶能够提高SBR/TPI并用硫化胶的拉伸强度和100%定伸应力,降低SBR/TPI并用硫化胶扯断伸长率;随着TPI并用量的增大,SBR/TPI并用硫化胶的压缩强度和压缩永久变形增大。

关 键 词:SBR/TPI  结晶  并用胶  硫化特性  物理性能

Effect of crystallinity of TPI on the properties of SBR/TPI blends vulcanized by CV system
ZHANG Zhi-guang,ZHANG Jun-ping,DU Ai-hua.Effect of crystallinity of TPI on the properties of SBR/TPI blends vulcanized by CV system[J].China Elastomerics,2011,21(3):1-5.
Authors:ZHANG Zhi-guang  ZHANG Jun-ping  DU Ai-hua
Affiliation:ZHANG Zhi-guang,ZHANG Jun-ping,DU Ai-hua (Key Laboratory of Rubber-Plastics,Ministry of Education,Qingdao University of Science and Technology,Qingdao 266042,China)
Abstract:The effect of crystallinity of TPI on the cure characteristics and physical properties of SBR/TPI blends vulcanized by CV system was investigated.The results showed that,crosslink density and curing rate of SBR/TPI blends increased,and scorch time of SBR/TPI compound was extended with the increasing amount of TPI.There was little influence of cold crystallization of TPI on the tensile properties of SBR/TPI blending vulcanizates.The tensile strength and modulus at 100% elongation of SBR/TPI blending vulcaniz...
Keywords:SBR/TPI  crystallinity  blend  cure characteristics  physical properties  
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