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Structure and dielectric performance of K-doped (Pb0.5Ba0.5)ZrO3 thin films
Authors:Xihong Hao  Jiwei Zhai  Zhenxing Yue  Xiwen Song  Shengli An
Affiliation:a Functional Materials Research Laboratory, Tongji University, Shanghai 200092, China
b School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou 014010, China
c State Key Laboratory of New Ceramic and Fine Processing Tsinghua University, Beijing 62772556, China
d State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
Abstract:In the present investigation (Pb0.5Ba0.5)ZrO3 (PBZ) thin films doped by K (KPBZ) from 0 to 5 mol% were successfully deposited on Pt-buffered silicon substrates by a sol-gel method. The K content dependence of microstructure and electrical properties of KPBZ thin films were studied in detail. It was found that, although all the films displayed a pure perovskite structure without obvious difference, the surface roughness of KPBZ films was decreased with increasing K content. Dielectric measurements showed that the figure of merit (FOM) values of KPBZ thin films were greatly increased by K-doping, and at the same time that the temperature-dependent stability was also improved. Thus, K doping is a promising way to optimize the overall electrical properties of PBZ thin films for potential application in tunable devices.
Keywords:A. Thin films   B. Sol-gel chemistry   D. Electrical properties
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