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含钒渣系活度计算模型及应用
引用本文:马登,吴巍,戴诗凡,刘质斌.含钒渣系活度计算模型及应用[J].材料与冶金学报,2017,16(4).
作者姓名:马登  吴巍  戴诗凡  刘质斌
作者单位:钢铁研究总院,北京,100081
基金项目:国家自然科学基金资助项目
摘    要:为研究转炉提钒的热力学,构建FeO-MgO-MnO-SiO_2-V_2O_3-Cr_2O_3-TiO_2七元渣系活度计算模型.利用此模型研究了影响钒渣中V_2O_3活度的因素,认为降低提钒终点温度,提高炉渣中的氧化铁含量,有利于降低钒渣中V_2O_3活度,提升转炉提钒的效率.通过活度模型计算得到,在低钒铁水和高钒铁水提钒过程中,碳钒临界转化温度分别为1313℃和1376℃.

关 键 词:FeO-MgO-MnO-SiO2-V2O3-Cr2O3-TiO2渣系  活度计算模型  临界转化温度

Activity-calculating model of vanadium slag system and its application
Ma Deng,Wu Wei,Dai Shifan,Liu Zhibin.Activity-calculating model of vanadium slag system and its application[J].Journal of Materials and Metallurgy,2017,16(4).
Authors:Ma Deng  Wu Wei  Dai Shifan  Liu Zhibin
Abstract:Activity-calculating model of FeO - MgO - MnO - SiO2 - V2O3 - Cr2O3 - TiO2 slag system was constructed and influencing factors of V2O3 activity and its activity coefficient were studied. The results showed that higher iron oxide or lower ending temperature can reduce V2O3 activity and increase vanadium extraction efficiency. It was found with the calculating model that the critical transition temperature between carbon and vanadium during vanadium extraction process is 1313 ℃ and 1376 ℃ for high vanadium hot metal and low vanadium hot metal respectively.
Keywords:FeO-MgO-MnO-SiO2 -V2O3 -Cr2O3 -TiO2 slag system  activity-calculating model  critical transition temperature
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