Preparation of V-doped TiO2 photocatalysts by the solution combustion method and their visible light photocatalysis activities |
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Authors: | Xiao Ma Lihong Xue Shengming Yin Miao Yang Youwei Yan |
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Affiliation: | 1. State Key Laboratory of Materials Processing and Die and Mould Technology, Huazhong University of Science and Technology, Wuhan, 430074, China
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Abstract: | A series of nanocrystalline V-doped (0.0–3.0 at.%) TiO2 catalysts have been successfully prepared by the one-step solution combustion method using urea as a fuel. The obtained powders were characterized by XRD, SEM, Raman, XPS and UV-Vis DRS. The effects of V doping concentration on the phase structure and photocatalytic properties were investigated. XRD, Raman, and XPS show that V doping diffuses into TiO2 crystal lattice mainly in the form of V5+ and causes a phase transition from anatase to rutile. V doping can widen the light absorption range of TiO2, with the absorption threshold wavelength shifting from 425 to 625 nm. The photocatalytic activity of V-doped TiO2 powders were evaluated by the photocatalytic degradation of methyl orange (MO) under visible light irradiation. It is found that V doping enhances the photocatalytic activity under visible light irradiation and the optimal degradation rate of MO is about 95.8% with 1.0 at% V-doped TiO2. |
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Keywords: | solution combustion titanium dioxide V doping photocatalyst |
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