The structural characterization and hydroformylation activity of the tri-rhodium complex [Rh3(μ2-dppm)2(μ2-CO)3(K-CO)3]BF4 |
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| Authors: | Fabio Lorenzini, Eoghain O&#x Hara, Shimeng Qian, Fabio Marchetti, James M. Birbeck, Anthony Haynes, Alexander J. Blake, Graham C. Saunders,Andrew C. Marr |
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| Affiliation: | Fabio Lorenzini, Eoghain O’Hara, Shimeng Qian, Fabio Marchetti, James M. Birbeck, Anthony Haynes, Alexander J. Blake, Graham C. Saunders,Andrew C. Marr, |
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| Abstract: | Rh2(cod)2(μ2-dppm)(μ2-Cl)]BF4 (1) rearranges under carbon monoxide to give [Rh3(μ2-dppm)2(μ2-CO)3(K1-CO)3]BF4 (2). Complex 2 has been structurally characterized by single crystal X-ray crystallography. The hydroformylation activities of 1 and 2 were compared for substrates styrene and 1-hexene and the activity of 2 found to be unexpectedly high. |
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| Keywords: | Binuclear Trinuclear Rhodium Hydroformylation |
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