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Synthesis and Characterization of Water-Borne Adhesives Based on 2-Ethylhexylacrylate-butylacrylate Copolymers Functionalized with Acrylic Acid
Abstract:ABSTRACT

A series of copolymers, based on 2-ethylhexylacrylate (2-EHA) and butylacrylate (BuA), and functionalized with small amounts of acrylic acid (AA) were synthesized by emulsion polymerization techniques and monodisperse latexes were obtained. Their average particle size and particle size distribution were determined by quasi-elastic light scattering and confirmed by transmission electron microscopy. The change in the adhesive properties (peel, shear, and tack) as a function of 2-EHA/BuA ratio was studied. An optimal balance between these three properties was determined at a 2-EHA/BuA ratio 10/90 wt/wt. The influence of the functionalization of these copolymers with AA was also evaluated when the comonomers ratio was kept constant. Good results were found at an AA content of 1 wt%.
Keywords:pressure-sensitive adhesives  water-borne adhesives  2-ethylhexylacrylate  butyl acrylate  acrylic acid
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