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EIS assessment of critical pitting temperature of 2205 duplex stainless steel in acidified ferric chloride solution
Affiliation:1. Metallurgical and Materials Engineering Department, Faculty of Engineering, Ferdowsi University of Mashhad, Mashhad 91775-1111, Iran;2. Materials Engineering Department, Hakim Sabzevari University, Sabzevar, Iran;1. Graduate School of Chemical Sciences and Engineering, Hokkaido University, Kita-13, Nishi-8, Kita-ku, Sapporo 060-8628, Japan;2. Faculty of Engineering, Hokkaido University, Kita-13, Nishi-8, Kita-ku, Sapporo 060-8628, Japan;3. Department of Materials Science and Engineering, Yonsei University, 134 Shinchon-Dong, Seodaemun-gu, Seoul 120-749, Republic of Korea;1. Laboratoire Sciences Analytiques Bioanalytiques et Miniaturisation, UMR CBI 8231, ESPCI ParisTech - CNRS, 10 rue Vauquelin, 75005 Paris, France;2. IFP Energies nouvelles, Rond-point de l’échangeur de Solaize, BP 3, 69360 Solaize, France;1. Corrosion and Protection Laboratory, Key Laboratory of Superlight Materials and Surface Technology (Harbin Engineering University), Ministry of Education, Nantong ST 145, Harbin 150001, China;2. Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Wencui RD 62, Shenyang 110016, China
Abstract:In this study, critical pitting temperature (CPT) of 2205 duplex stainless steel (DSS2205) was assessed using electrochemical impedance spectroscopy (EIS) in ferric chloride solution. In order to verify the results other methods such as ASTM G 48, potentiodynamic and potentiostatic polarisation and zero resistance ammeter (ZRA) were also employed. The results show a strong close relation between the results of this method by those of previous methods. CPT of the alloy is 40 °C based on standard method and 44 °C, 49 °C according to the ZRA and potentiostatic methods. Both potentiodynamic and EIS methods give an almost identical CPT value.
Keywords:A. Stainless steel  B. EIS  B. Polarisation  C. Pitting corrosion
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