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Two dication salts of ET: preparation and crystal structures of ET [FeII(CN)4(CO)2]
Affiliation:1. Laboratory of Organic Solids, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, PR China;2. Graduate School of Chinese Academy of Sciences, Beijing, PR China;1. LCC-CNRS, Université de Toulouse, CNRS, UPS, Toulouse, France;2. Université de Paris, Laboratoire Matériaux et Phénomènes Quantiques (UMR 7162 CNRS), 75205 Paris Cedex 13, France;3. Université Paris-Saclay, CNRS, Laboratoire de Physique des Solides, 91405, Orsay, France;1. School of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104, China;2. School of Materials Science and Engineering, Central South University, Changsha 410083, China;3. Key Laboratory of Nonferrous Metals Materials Science and Engineering, Ministry of Education, Central South University, Changsha 410083, China;1. Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska 64/13, 01601 Kyiv, Ukraine;2. Max-Planck Institute for Chemical Energy Conversion, Stiftstr. 34-36, D-45470 Mülheim an der Ruhr, Germany;3. Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstraße 4, D-37077 Göttingen, Germany;4. Department of Chemistry, University of Jyväskylä, PO Box 35, FI-40014 Jyväskylä, Finland;1. College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing 210009, PR China;2. Technology and Finance Service Center of Jiangsu Province, Productivity Center of Jiangsu Province, Nanjing 210042, PR China
Abstract:Single crystals of new dication bis(ethylenedithio)tetrathiafulvalene salts with FeII(CN)4(CO)2]2− were prepared electrochemically. Two kind crystals (A and B) with the same composition and different stacking patterns were derived from Na2FeII(CN)4(CO)2] and TBA2FeII(CN)4(CO)2], respectively.
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