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Selective N-monomethylation of aniline with dimethyl carbonate over Y-zeolites
Authors:Zi-hua Fu  Yoshio Ono
Affiliation:(1) Department of Chemical Engineering, Tokyo Institute of Technology, Ookayama, Meguro-ku, 152 Tokyo, Japan
Abstract:The methylation of aniline with dimethyl carbonate was studied and a very high selectivity for N-monomethylation was attained over alkali cation exchanged zeolites. Thus, a 93.5% selectivity for N-methylaniline was obtained at aniline conversion at 99.6% over KY at 453K.
Keywords:Aniline  methylation  dimethyl carbonate  zeolite
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