Selective N-monomethylation of aniline with dimethyl carbonate over Y-zeolites |
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Authors: | Zi-hua Fu Yoshio Ono |
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Affiliation: | (1) Department of Chemical Engineering, Tokyo Institute of Technology, Ookayama, Meguro-ku, 152 Tokyo, Japan |
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Abstract: | The methylation of aniline with dimethyl carbonate was studied and a very high selectivity for N-monomethylation was attained over alkali cation exchanged zeolites. Thus, a 93.5% selectivity for N-methylaniline was obtained at aniline conversion at 99.6% over KY at 453K. |
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Keywords: | Aniline methylation dimethyl carbonate zeolite |
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