| 催化裂化柴油和焦化柴油中烯烃类型及分布表征 |
| |
| 引用本文： | 白雪,刘泽龙.催化裂化柴油和焦化柴油中烯烃类型及分布表征[J].石油炼制与化工,2011,42(11):76-80. |
| |
| 作者姓名： | 白雪 刘泽龙 |
| |
| 作者单位： | 石油化工科学研究院; |
| |
| 基金项目： | 国家重点基础研究发展计划“973”项目 |
| |
| 摘 要： | 制备了Ag-SiO2固定相。采用固相萃取(SPE)技术分离催化裂化柴油和焦化柴油中的烯烃， GC/MS和1H NMR表征烯烃的类型和碳数分布。结果表明：催化裂化柴油和焦化柴油中的烯烃类型主要包括正构α-烯烃、内单烯烃、双烯烃和环烯烃；催化裂化柴油烯烃中的内烯氢摩尔分数为80.41%；而焦化柴油中的正构α-烯氢摩尔分数为53.32%；催化裂化柴油中的烯烃碳数集中在C11～C15，焦化柴油中的烯烃碳数集中在C12～C22。
|
| 关 键 词： | 柴油 烯烃 固相萃取 质谱分析 核磁共振波谱 |
| 收稿时间： | 2011-4-6 |
| 修稿时间： | 2011-5-30 |
CHARACTERIZATION OF ALKENE TYPES AND DISTRIBUTIONS IN FCC DIESEL AND COKER DIESEL FUEL |
| |
| Bai Xue,Liu Zelong.CHARACTERIZATION OF ALKENE TYPES AND DISTRIBUTIONS IN FCC DIESEL AND COKER DIESEL FUEL[J].Petroleum Processing and Petrochemicals,2011,42(11):76-80. |
| |
| Authors: | Bai Xue Liu Zelong |
| |
| Affiliation: | Bai Xue,Liu Zelong(Research Institute of Petroleum Processing,SINOPEC,Beijing 100083) |
| |
| Abstract: | An Ag-SiO2 stationary phase was prepared and applied in solid phase extraction(SPE) technique to separate alkenes from FCC diesel fractions and coker diesel fractions.GCMS and 1H NMR were used to characterize the types and carbon number distributions of the separated alkenes.Test results showed that normal α-olefin,internal monoolefin,diolefin and cycloolefin were the main types of alkenes in FCC diesel fractions and coker diesel fractions.The mole fraction of internal-ene hydrogen in FCC diesel fractions was 80.41%,and the mole fraction of normal α-ene hydrogen in coker diesel fractions was 53.32%.The distributions of alkenes in FCC diesel fractions and coker diesel fractions were focused on C11—C15 and C12—C22,respectively. |
| |
| Keywords: | diesel alkene solid phase extraction mass spectrometry analysis nuclear magnetic resonance |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《石油炼制与化工》浏览原始摘要信息 |
|
点击此处可从《石油炼制与化工》下载全文 |
