| 双酚S的合成与分离 |
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| 引用本文： | 金范龙 曾维新. 双酚S的合成与分离[J]. 吉林化工学院学报, 1996, 13(1): 18-21 |
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| 作者姓名： | 金范龙 曾维新 |
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| 作者单位： | 吉林化工学院，吉化公司染料厂 |
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| 摘 要： | 以活性炭作催化剂、二氯苯与乙醇作混合有机溶剂、用浓硫酸直接磺化苯酚的方法制备工业级的双酚Ｓ．经正交实验和单因素优化得反应温度１８５℃～１９５℃，反应时间３～５ｈ，苯酚与浓硫酸的摩尔比为１：２．１～３．０．活性炭用量２ｇ～４ｇ．用于萃取精制的混合二氯苯与乙醇有机溶剂可蒸馏回收．
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| 关 键 词： | 双酚S；苯酚；磺化；萃取；活性炭；正交实验 |
THE SYNTHESIS AND SEPARATION OF BISPHENOL S |
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| Jin Fanlong,Yi Shouzhi,Wang Guangquan. THE SYNTHESIS AND SEPARATION OF BISPHENOL S[J]. Journal of Jilin Institute of Chemical Technology, 1996, 13(1): 18-21 |
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| Authors: | Jin Fanlong Yi Shouzhi Wang Guangquan |
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| Affiliation: | Jin Fanlong;Yi Shouzhi;Wang Guangquan (Jilin Institute of Chemical Technology) Zeng Weixin(Dye Plant of Jilin Chemical Industry Corporation) |
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| Abstract: | The industrial standard bisphenol S is synthesized by sulfonating phenol with concentrated sulphuric acid,using dichiorobenzene and ethanol as mixed organic solvent and activated carbon as catalyst.By orthogonal tests and single factor optimization,the technological conditions are determined with reaction temperature 185℃～195℃,reaction time 3h～5h,moles ratio of phenol and concentrated sulphuric acid 1:2.1～3.0 and quantity of activated carbon 2g～4g.The mixed organic solvent of dichlorobenzene and ethanol for extraction refinement can be recovered by distillation. |
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| Keywords: | bisphenol S phenol sulfonation extraction activated carbon orthogonal test |
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