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半绝缘InP的铁掺杂激活与电学补偿
引用本文:苗杉杉,赵有文,董志远,邓爱红,杨俊,王博.半绝缘InP的铁掺杂激活与电学补偿[J].半导体学报,2006,27(11):1934-1939.
作者姓名:苗杉杉  赵有文  董志远  邓爱红  杨俊  王博
作者单位:四川大学物理学院 应用物理系,成都 610065;中国科学院半导体研究所,北京 100083;中国科学院半导体研究所,北京 100083;四川大学物理学院 应用物理系,成都 610065;四川大学物理学院 应用物理系,成都 610065;四川大学物理学院 应用物理系,成都 610065
摘    要:比较了掺Fe和非掺退火半绝缘(SI)InP材料中Fe杂质的分布,掺杂激活机理以及Fe原子与点缺陷的相互作用.原生掺Fe SI-InP中Fe的替位激活主要通过填隙-跳跃机制,但Fe原子易在位错周围聚集,与空位形成复合体缺陷,占据填隙位等,从而降低Fe的激活效率.在FeP2气氛下退火非掺InP获得的SI-InP材料中,Fe原子的激活主要通过扩散过程的"踢出-替位"机制.退火前材料中存在的In空位使Fe原子通过扩散充分占据In位,同时抑制了材料中深能级缺陷的形成.因此,这种SI-InP材料的Fe激活效率高、电学性能好.

关 键 词:InP  铁激活  退火  半绝缘  半绝缘  铁掺杂  激活机理  电学补偿  Compensation  Electrical  Fe  Doping  电学性能  深能级缺陷  扩散过程  存在  跳跃机制  效率  体缺陷  空位  聚集  相互作用  点缺陷  原子  分布
文章编号:0253-4177(2006)11-1934-06
收稿时间:03 29 2006 12:00AM
修稿时间:05 22 2006 12:00AM

Activation of Fe Doping and Electrical Compensation in Semi-Insulating InP
Miao Shanshan,Zhao Youwen,Dong Zhiyuan,Deng Aihong,Yang Jun and Wang Bo.Activation of Fe Doping and Electrical Compensation in Semi-Insulating InP[J].Chinese Journal of Semiconductors,2006,27(11):1934-1939.
Authors:Miao Shanshan  Zhao Youwen  Dong Zhiyuan  Deng Aihong  Yang Jun and Wang Bo
Affiliation:Department of Applied Physics,Faculty of Science,Sichuan University,Chengdu 610065,China;Institute of Semiconductors,Chinese Academy of Sciences,Beijing 100083,China;Institute of Semiconductors,Chinese Academy of Sciences,Beijing 100083,China;Department of Applied Physics,Faculty of Science,Sichuan University,Chengdu 610065,China;Department of Applied Physics,Faculty of Science,Sichuan University,Chengdu 610065,China;Department of Applied Physics,Faculty of Science,Sichuan University,Chengdu 610065,China
Abstract:The impurity distribution,doping activation mechanism,and interaction between Fe atoms and point defects in Fe-doped and annealed undoped semi-insulating(SI) InP materials are compared.The substitution and activation of Fe occur mostly via an interstitial hopping mechanism in as-grown Fe-doped SI InP.However,Fe atoms aggregate around dislocations and form complex defects with vacancies.The concentration of Fe atoms at interstitial positions is very high,resulting in a low activation efficiency.The activation mechanism of Fe is a kick-out substitution process in SI material obtained by annealing undoped InP in an iron phosphide ambient.Fe atoms nearly completely occupy the indium lattice sites due to the indium vacancy in the material before annealing.The formation of deep level defects is suppressed in the annealing process.This results in high Fe activation efficiency and good electrical properties of the SI-InP material.
Keywords:InP  Fe activation  annealing  semi-insulating
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