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阳离子聚合物在多孔介质中的水动力学吸附
引用本文:刘建新,张营华,任韶然.阳离子聚合物在多孔介质中的水动力学吸附[J].石油化工高等学校学报,2009,22(1):41-44.
作者姓名:刘建新  张营华  任韶然
作者单位:中国石油大学(华东)石油工程学院,山东东营257061
基金项目:山东省泰山学者建设基金 
摘    要:为研究聚合物和盐水注入速度对阳离子聚合物在多孔介质中吸附的影响,用碳化硅颗粒制作填砂模型,进行了恒温驱替实验,根据测试的残余阻力系数计算不同注入速度下的聚合物吸附层厚度。结果表明,阳离子聚合物在多孔介质中的吸附主要受静电引力和水动力的影响。在低的聚合物注速时,静电引力起主导作用;而在较高注速时,水动力起主导作用。聚合物注入速度增加,吸附层厚度呈线性增加,从 290 nm增加到 1 510 nm。盐水注入速度(后置液)对吸附层厚度也有一定影响,吸附层厚度随盐水注速增加而增加。提高聚合物溶液和后置盐水溶液的注入速度,有利于改善地层岩石的聚合物吸附能力,提高堵水效果。

关 键 词:阳离子聚合物      水动力学吸附      阻力系数      残余阻力系数      吸附层  
收稿时间:2008-06-30

Hydrodynamic Adsorption of Cationic Polymer in Porous Media
LIU Jian-xin,ZHANG Ying-hua,REN Shao-ran.Hydrodynamic Adsorption of Cationic Polymer in Porous Media[J].Journal of Petrochemical Universities,2009,22(1):41-44.
Authors:LIU Jian-xin  ZHANG Ying-hua  REN Shao-ran
Affiliation:(College of Petroleum Engineering, China University of Petroleum, Dongying Shandong 257061, P. R. China)
Abstract:Core flood experiments were carried out using unconsolidated SiC sand packs at different injection rates under isothermal conditions. The thickness of adsorbed polymer layers could be calculated from the residual resistance factors measured in core flood experiments. The results show that adsorption of cationic polymers in pbrous media is affected mainly by electrostatic attraction and hydrodynamic forces. At low polymer injection rates, polymer adsorption is dominated by electrostatic forces, while it is dominated by hydrodynamic forces at higher polymer injection rates. The adsorbed layer thickness increases linearly from 290 to 1 510 nm with polymer injection rates. The adsorbed layer thickness is also affected by the brine injection rate in back flush: high brine injection rate can increase the adsorption. Therefore, the adsorption of polymers can be improved using higher rates in squeezing both polymer and back- flush brine solutions, and so the water control efficiency.
Keywords:Cationic polymer  Hydrodynamic adsorption  Resistance factor  Residual resistance factor  Adsorbed layer
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