| 长链正构烯烃中双烯选择加氢负载铁催化、剂的研究 |
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| 引用本文： | 卢振举,王承玉,梁东白,林励吾.长链正构烯烃中双烯选择加氢负载铁催化、剂的研究[J].石油化工,1991(7). |
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| 作者姓名： | 卢振举 王承玉 梁东白 林励吾 |
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| 作者单位： | 中国科学院大连化学物理研究所，中国科学院大连化学物理研究所，中国科学院大连化学物理研究所，中国科学院大连化学物理研究所 大连 116023，大连 116023，大连 116023，大连 116023 |
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| 摘 要： | 报道了经硫化的Fe/γ-Al_2O_3对长链正构烯烃中双烯选择加氢性能的影响,通过硫含量与加氢性能的考察和使用TPR和穆斯堡尔谱仪对样品的测试,发现样品中的Fe_(1-x)S_(0
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Study of Fe/Al_2O_3 Catalyst for Selective Hydrogenation of Diolefines in Linear Internal Olefins |
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| Abstract: | A new type of Fe/γ-Al_2O_3 catalyst is developed for selective hydrogenation of diolefins in linear internal olefins. The performance of the catalyst is featured by its excellent activity and good selectivity.The properties of the activated catalyst are investigated by temperature program reduction(TPR) and Mossbauer spectroscopy (MS). The results indicate that before sulfurization the iron on the support is Fe_2O_3 phase. When the catalyst is sulfurized Fe_2O_3 phase changes into Fe_(1-x)S phase. Increase in selectivity of catalyst occurs with increase of Fe_(1-x)S phase. |
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