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Atomic-layer-deposited Al2O3 and HfO2 on GaN: A comparative study on interfaces and electrical characteristics
Authors:Y.C. ChangM.L. Huang  Y.H. ChangY.J. Lee  H.C. ChiuJ. Kwo  M. Hong
Affiliation:a Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan
b Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan
c Center for Condensed Matter Sciences, National Taiwan University, Taipei 10617, Taiwan
Abstract:Al2O3, HfO2, and composite HfO2/Al2O3 films were deposited on n-type GaN using atomic layer deposition (ALD). The interfacial layer of GaON and HfON was observed between HfO2 and GaN, whereas the absence of an interfacial layer at Al2O3/GaN was confirmed using X-ray photoelectron spectroscopy and transmission electron microscopy. The dielectric constants of Al2O3, HfO2, and composite HfO2/Al2O3 calculated from the C-V measurement are 9, 16.5, and 13.8, respectively. The Al2O3 employed as a template in the composite structure has suppressed the interfacial layer formation during the subsequent ALD-HfO2 and effectively reduced the gate leakage current. While the dielectric constant of the composite HfO2/Al2O3 film is lower than that of HfO2, the composite structure provides sharp oxide/GaN interface without interfacial layer, leading to better electrical properties.
Keywords:MOS   Atomic-layer-deposition (ALD)   HfO2   Al2O3   GaN   High k dielectric
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