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Low temperature direct imprint of polyhedral oligomeric silsesquioxane (POSS) resist
Authors:Nikolaos Kehagias  Marc ZelsmannMustapha Chouiki  Achille FranconeVincent Reboud  Rainer SchoeftnerClivia Sotomayor Torres
Affiliation:a Phononic and Photonic Nanostructures Group, Catalan Institute of Nanotechnology (CIN2-CSIC), Campus Bellaterra - Edifici CM3, 08193-Bellaterra, Barcelona, Spain
b LTM-CNRS, CEA-LETI-MINATEC, 17 rue des Martyrs 38000, Grenoble, France
c PROFACTOR GmbH, Functional Surfaces and Nanostructures, 4407 Steyr-Gleink, Austria
d Catalan Institute for Research and Advanced Studies ICREA, 08010 Barcelona, Spain
Abstract:In this paper we present results on the synthesis of a hybrid organic/inorganic resist based on polyhedral oligomeric silsesquioxane cages and used it in a thermal nanoimprint lithography process. Our resist has been developed in order to be uniformly spin coated on silicon substrates, imprinted at a reduced temperature (40 °C), then cross-linked first at elevated temperatures (>120 °C) during the imprinting process and then by exposure to UV radiation outside the imprinting tool. With this process, a low shrinkage rate of the resist is achieved after cross-linking, combined with high mechanical and thermal properties.
Keywords:Nanoimprint lithography  Polyhedral silsesquioxane (POSS) resist
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