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Experimental investigation of thermal insulating aerogel composites of hydrothermal reactor for biomass-to-hydrogen conversion
Authors:A.D. Vedenin  P.A. Vityaz  I.S. Ivanova  Yu.A. Mazalov  A.P. Pustovgar  L.V. Sudnik
Affiliation:1. GOSNITI, 1st Institutskiy Passage, Moscow, 109428, Russia;2. National Academy of Sciences of Belarus, 66, Independence Ave., Minsk, 220072, Belarus;3. Scientific Research Institute of Building Materials and Technologies, Moscow State University of Civil Engineering, 26 Yaroslavl Highway, Moscow, 129337, Russia;4. Scientific Research Institute of the Pulse Processes of Powder Metallurgy Institute of National Academy of Sciences, 41, St. Platonov, Minsk, 220005, Belarus
Abstract:The paper presents aerogel SiO2–TiO2 composites used for thermal insulation of hydrothermal reactor for biomass-to-hydrogen conversion and the method of their production. The technology of aerogel composites production includes the following stages: ion exchange of liquid Na-glass resulting in production of silica hydrosol; hydrosol concentration; hydrogel production and its maturing; SiO2–TiO2 alcogel production; modification of its surface; subcritical drying of alcogel resulting in production of SiO2–TiO2 ambigel; its thermal treatment, granulating and classification. The influences of infrared opacifier (titanium dioxide) and thermal treatment temperature of SiO2–TiO2 composite on its structural and thermal characteristics have been investigated. Possibilities of hydrogen yield increase by reduction of power waste by means of vacuumized thermal insulation for reactor walls have been examined.
Keywords:Hydrothermal reactor  Biomass-to-hydrogen conversion  Vacuumized thermal insulation  Hydrothermal processes  Hydrogen  Aerogel composites  Heat conductivity  Hydrogen power
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