| Grignard反应一步法合成二环己基二甲氧基硅烷 |
| |
| 引用本文： | 赵冬冬,金炼铁.Grignard反应一步法合成二环己基二甲氧基硅烷[J].当代化工,2011(8):781-783. |
| |
| 作者姓名： | 赵冬冬 金炼铁 |
| |
| 作者单位： | 武汉工程大学化学与制药学院; |
| |
| 摘 要： | 采用Grignard反应一步法合成了二环己基二甲氧基硅烷.14 g镁屑、11g氯代环己烷和30 g THF投入反应瓶,在回流状况下滴加由36.4 g四甲氧基硅烷、44 g氯代环己烷和120 g石油醚90～120组成的混合溶液；回流4h后冷却,过滤；母液精馏得产物55 g,收率86.9％(以四甲氧基硅烷计),质量分数≥9...
|
| 关 键 词： | 二环己基二甲氧基硅烷 氯代环己烷 四甲氧基硅烷 给电子体 |
Synthesis of Dicyclohexyldimethoxysilane by One-step Grignard Reaction Method |
| |
| ZHAO Dong-dong,JIN Lian-tie.Synthesis of Dicyclohexyldimethoxysilane by One-step Grignard Reaction Method[J].Contemporary Chemical Industry,2011(8):781-783. |
| |
| Authors: | ZHAO Dong-dong JIN Lian-tie |
| |
| Affiliation: | ZHAO Dong-dong,JIN Lian-tie (School of Chemical Engineering&Pharmacy,Wuhan Institute of Technology,Hubei Wuhan 430074,China) |
| |
| Abstract: | Dicyclohexyldimethoxysilane was synthesized by one step Grignard reaction method.Firstly,14 g magnesium,11 g chlorocyclohexane and 30 g THF were added into the flask.Then 36.4 g tetramethoxysilane,44 g chlorocyclohexane and 120 g petroleum ether 90～120 were added to the system in the case of reflux.After 4 h,55 g dicyclohexyldimethoxysilane was obtained by separation and rectification.The yield was 86.9%,the purity was 99%. |
| |
| Keywords: | Dicyclohexyldimethoxysilane Chlorocyclohexane Tetramethoxysilane Donor |
| 本文献已被 CNKI 维普 等数据库收录！ |
