| 电流辅助加热条件下Ti_3AlC_2/Zr连接界面研究 |
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| 引用本文： | 杨 辉,卢 博,杨贤金,史 文,周小兵,李 鹏,黄 峰,黄 庆.电流辅助加热条件下Ti_3AlC_2/Zr连接界面研究[J].现代技术陶瓷,2017,38(1):48-56. |
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| 作者姓名： | 杨 辉 卢 博 杨贤金 史 文 周小兵 李 鹏 黄 峰 黄 庆 |
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| 作者单位： | 中国科学院宁波材料技术与工程研究所，浙江 宁波315201;上海大学 材料科学与工程学院，上海200072,中国科学院宁波材料技术与工程研究所，浙江 宁波315201;天津大学 材料科学与工程学院，天津300072,天津大学 材料科学与工程学院，天津300072,上海大学 材料科学与工程学院，上海200072,中国科学院宁波材料技术与工程研究所，浙江 宁波315201,中国科学院宁波材料技术与工程研究所，浙江 宁波315201,中国科学院宁波材料技术与工程研究所，浙江 宁波315201,中国科学院宁波材料技术与工程研究所，浙江 宁波315201 |
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| 基金项目： | 国家自然科学基金 (91426304；91426304)；中科院跨学科创新团队；中国科学院战略重点研究项目 (XDA03010305)；浙江省自然科学基金 (LY15E020007)。 |
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| 摘 要： | 采用电场辅助加热技术实现了Ti_3AlC_2/Zr的低温连接,并对其界面结构进行了研究。在TAC/Zr连接对中,Al的扩散激活能只有6.9 k J/mol,远低于传统的热压方法连接Ti_2AlC-Zr时Al的扩散激活能。TiC做过渡层时可以有效地抑制Al从Ti_3AlC_2一侧向Zr合金中扩散,并且可以进一步降低连接温度。研究发现,通过调控TiC涂层的计量比以调控连接界面的性能是完全有可能的。
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| 关 键 词： | Ti3AlC2 扩散连接 电场辅助 TiC中间层 |
Interlayer-Mediated Interface Bonding of Zr and Ti3AlC2 Through Electric-Current-Aided Heating |
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| YANG Hui,LU Bo,YANG Xian-Jin,SHI Wen,ZHOU Xiao-Bing,LI Peng,HUANG Feng and HUANG Qing.Interlayer-Mediated Interface Bonding of Zr and Ti3AlC2 Through Electric-Current-Aided Heating[J].Advanced Ceramics,2017,38(1):48-56. |
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| Authors: | YANG Hui LU Bo YANG Xian-Jin SHI Wen ZHOU Xiao-Bing LI Peng HUANG Feng and HUANG Qing |
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| Affiliation: | Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Science, Ningbo 315201, China;School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China,Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Science, Ningbo 315201, China;School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China,School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China,School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China,Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Science, Ningbo 315201, China,Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Science, Ningbo 315201, China,Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Science, Ningbo 315201, China and Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Science, Ningbo 315201, China |
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| Abstract: | Electric-current-aided heating was employed to realize the Ti3AlC2/Zr joining at low temperature and the interface structure was studied. The diffusion activation energy of Al element in the prepared TAC/Zr joining couple is only 6.9 kJ/mol, being much lower than that in Ti2AlC/Zr joining couple by traditional pressure sintering, 38 kJ/mol. When TiC coating is used as an interlayer, it was found that the TiC interlayer can efficiently block the diffusion of Al from Ti3AlC2 side into Zr alloy without the deterioration of joining behavior. The results also show that the joining temperature for TiC@TAC/Zr couple was further reduced. While, the TiC interlayer have revealed the promising role to control the interface reaction through the regulation of ratio of Ti and C in the coating. |
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| Keywords: | Ti3AlC2 Diffusion bonding Electric-current-aided TiC interlayer |
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