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Probing intermediates in the reaction of ethylene over supported Ru; use and limitations of multiple quantum spin counting |
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| Authors: | Son -Jong Hwang T. S. King B. C. Gerstein |
| Affiliation: | (1) Department of Chemistry and Ames Laboratory, Iowa State University, 229 Spedding Hall, 50011 Ames, IA, USA;(2) Department of Chemical Engineering and Ames Laboratory, Iowa State University, 231 Sweeney Hall, 50011 Ames, IA, USA |
| Abstract: | Multiple quantum spin counting is shown to yield an upper limit ofn = 6 for strongly bound, rigid intermediates CmHn in the reaction of ethylene over Ru/SiO2. The results eliminate the possibility of major components of such intermediates being polymer-like coke precursers. A precurser to 2-butene is one possible intermediate. |
| Keywords: | Ethylene on ruthenium 13C NMR multiple quantum spin counting |
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