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Short-term electrochemical corrosion behavior of pipeline steel in saline sandy environments
Affiliation:1. College of Architecture and Civil Engineering, Taiyuan University of Technology, Taiyuan 030024, P. R. China;2. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, P. R. China;3. Department of Civil Engineering, Monash University, Clayton, Victoria 3800, Australia;4. State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Hohai University, Nanjing 210098, P. R. China;1. Faculty of Mechanical Engineering, Technical University of Kosice, Letna 9, 042 00, Kosice, Slovak Republic;2. Technical University of Kosice, Letna 9, 042 00, Kosice, Slovak Republic
Abstract:In this study, we investigate the short-term electrochemical corrosion behavior of X70 pipeline steel in salinized sandy soil using the electrochemical impedance spectroscopy (EIS). The results show that the corrosion behavior of X70 steel in sandy soils with a relatively high water content (~ 18%) is mainly dominated by pitting or localized corrosion, which is controlled by charge-transfer processes. The reason can be attributed to the loose corrosion products (unable to produce an effective protective layer) and discontinuous gradation in sand particles. EIS plots of X70 steel consist of two capacitive loops at the initial stage of corrosion, while a capacitive arc at high-, medium-, and low-frequency is developed after 12 h of corrosion. The capacitive loop formed at the high frequency indicates the resistance and capacitance generated by the penetration of ions into the metal surface through the sand pores and the defects of the corrosion product film.
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