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Microanalyses on the RuO2 Particle–Glass Matrix Interface in Thick-Film Resistors with Piezoresistive Effects
Authors:Masashi Totokawa  Syuichi Yamashita  Kenji Morikawa  Yoshihito Mitsuoka  Toshihiko Tani   Hiroaki Makino
Affiliation:Denso Corporation, Kariya, Aichi 448-8661, Japan;
Toyota Technological Institute, Nagoya 468-8511, Japan;
Denso Corporation, Kariya, Aichi 448-8661, Japan;
Toyota Technological Institute, Nagoya 468-8511, Japan;
Toyota Central R&D Labs Inc., Nagakute, Aichi 480-1192, Japan;
Toyota Central R&D Labs Inc., Nagakute, Aichi 480-1192, Japan
Abstract:The piezoresistive mechanisms of composite thick films based on RuO2 particles and both calcium-borosilicate and bismuth-borosilicate glass matrices were investigated by chemical and electrical microanalyses. The resistor based on bismuth-borosilicate glass showed higher sensitivity than that based on calcium-borosilicate glass. It was confirmed that the diffusion of ruthenium into glass affects the binding state of RuO2 at the interface of the glass. Furthermore, an intermediate resistive layer is detected around the RuO2 particle. These results suggest that the piezoresistive effect is related to a change in the electrical conductivity of the interfacial reaction layer caused by the diffusion of ruthenium into glass.
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