| 1,1,2,3-四氯丙烯氟化合成2,3,3,3-四氟丙烯过程热力学分析 |
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| 引用本文： | 谢遵运,彭小波,王月娟,罗孟飞.1,1,2,3-四氯丙烯氟化合成2,3,3,3-四氟丙烯过程热力学分析[J].有机氟工业,2011(3):40-44. |
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| 作者姓名： | 谢遵运 彭小波 王月娟 罗孟飞 |
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| 作者单位： | 浙江省固体表面反应化学重点实验室浙江师范大学物理化学研究所; |
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| 摘 要： | 介绍了第四代制冷剂2,3,3,3-四氟丙烯（HFO-1234yf）的优点及合成过程。以热力学为基础,对1,1,2,3-四氯丙烯氟化合成2,3,3,3-四氟丙烯过程的反应进行了计算,并运用计算的结果对专利中所选择的反应条件进行了热力学分析。
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| 关 键 词： | 1 1 2 3-四氯丙烯 2 3 3 3-四氟丙烯 热力学计算 热力学分析 |
Thermodynamic Analysis on the Process for Synthesis of 2,3,3,3-Tetrafluoropropene from 1,1,2,3-Tetrachloropropene |
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| Xie Zunyun,Peng Xiaobo,Wang Yuejuan,Luo Mengfei.Thermodynamic Analysis on the Process for Synthesis of 2,3,3,3-Tetrafluoropropene from 1,1,2,3-Tetrachloropropene[J].Organo-Fluorine Industry,2011(3):40-44. |
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| Authors: | Xie Zunyun Peng Xiaobo Wang Yuejuan Luo Mengfei |
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| Affiliation: | Xie Zunyun,Peng Xiaobo,Wang Yuejuan,Luo Mengfei(Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces,Institute of Physical Chemistry,Zhejiang Normal University,Jinhua 321004) |
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| Abstract: | Advantages of the fourth-generation refrigerant 2,3,3,3-tetrafluoropropene(HFO-1234yf) and it's synthesis process were introduced.Thermodynamics of the synthesis of 2,3,3,3-tetrafluoropropene from 1,1,2,3-tetrachloropropene was calculated,which was also applied to the conditions reported in published patents. |
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| Keywords: | 1 2 3-tetrachloropropene 3 3-tetrafluoropropene thermodynamic calculation thermodynamic analysis |
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