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Electroless Ni-Co-P Coating of Cenospheres Using Ag(NH_3)_2~+ Activator
作者姓名:ZENG Ai-xiang w  XIONG Wei-hao * .
作者单位:ZENG Ai-xiang w,XIONG Wei-hao * 1. Department of Chemistry,Changsha University of Science and Technology,Changsha,China 2. State Kay Laboratory of Die &Mould Technology,Huazhong University of Science and Technology,Wuhan,China
基金项目:湖南省自然科学基金,湖南省教育厅科研项目
摘    要:FLY ASH CENOSPHERES are primarily a by-productin power generation plants.Research is in progress toeffectively use this by-product to produce new usableand profitable materials as they pose major disposaland environmental problems.Fly ash cenospheres areunique,property stable,non-toxic,non-metallic hollowmicro-particles.Due to the unique hollow structure andphysical mechanics properties,Cu^Ag and other metalsare often coated on cenospheres to produce lightweightmetal matrix composites,w…


Electroless Ni-Co-P Coating of Cenospheres Using Ag(NH3)2+ Activator
ZENG Ai-xiang w,XIONG Wei-hao * ..Electroless Ni-Co-P Coating of Cenospheres Using Ag(NH_3)_2~+ Activator[J].Transactions of Materials and Heat Treatment,2004,25(5).
Authors:ZENG Ai-xiang  XIONG Wei-hao
Affiliation:1. Department of Chemistry, Changsha University of Science and Technology, Changsha, China;State Kay Laboratory of Die &Mould Technology, Huazhong University of Science and Technology, Wuhan, China
2. State Kay Laboratory of Die &Mould Technology, Huazhong University of Science and Technology, Wuhan, China
Abstract:Electroless Ni-Co-P-coating of fly-ash cenosphere particles is demonstrated in the present investigation. The Electroless Ni-Co-P-coating process is modified by replacing the conventional sensitization and activation steps with only using activation step with Ag(NH3)2+ activator. The cenospheres are characterized by scanning electron microscope (SEM), energy dispersive spectroscopy (EDX), X-ray diffraction analysis (XRD) and X-ray photoelectron spectroscopy (XPS) during and after the coating process. Relatively uniform coating is obtained under the given coating conditions. The possible mechanism of electroless Ni-Co-P-coating of cenospheres utilizing Ag(NH3)2+ activator is suggested. The low density Ni-Co-P coated cenospheres may be utilized for manufacturing conducting polymers for EMI-shielding application and microwave absorbing materials.
Keywords:Ni-Co-P coating  fly ash cenopsphere particles  Ag(NH3)2+ activator  electroless plating
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