Effect of lanthanum hydride on microstructures and hydrogen storage performances of 2LiNHe-MgH2 system |
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| Authors: | ZHU Xilin HAN Shumin ZHAO Xin LI Yuan LIU Baozhong |
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| Affiliation: | [1]College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, China [2]State Key Laboratory of Metastable MaterialsScience and Technology, Yanshan University, Qinhuangdao 066004, China [3]School of Materials Science and Engineering, Henan Polytechnic University,Jiaozuo 454000, China |
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| Abstract: | Hydrogen storage properties of 2LiNH2-MgH2 system were improved by adding lanthanum hydride (LaH3), and the role of LaH3 in hydrogen sorption process of Li-Mg-N-H system was investigated. Temperature programmed sorption results showed that the addition of lanthanum hydride reduced the dehydriding/hydriding onset temperature of 2LiNH2-MgH2 system by at least 15 K. Moreover, A 0.053 wt.%/min average rate was determined for the hydrogen desorption of 2LiNH2-MgH2-0.05LaH3 composite, while it was only 0.035 wt.%/min for 2LiNH2-MgH2 system. Hydrogen absorption capacity increased from 1.62 wt.% to 2.12 wt.% within 200 min by adding LaH3 into 2LiNH2-MgH2 system at 383 K. In the dehydrogenation of 2LiNH2-MgH2-0.05LaH3 composite, LaH2 transferred to LaN phase, which reversed to LaH2 in the following hydrogen adsorption process. The reversible reaction of LaH2 effectively promoted the hydrogen sorption of Li-Mg-N-H system. Moreover, the homogenous distribution of fine La hydride was favorable to improving effect of lanthanum hydride. |
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| Keywords: | hydrogen storage performances Li-Mg-N-H system lanthanum hydride kinetics rare earths |
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