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Core–shell nanoscale precipitates in Al–0.06 at.% Sc microalloyed with Tb,Ho, Tm or Lu
Authors:Matthew E Krug  Alexandra Werber  David C Dunand  David N Seidman
Affiliation:1. Northwestern University, Materials Science and Engineering, 2220 Campus Drive, Northwestern University, Evanston, IL 60208-3108, USA;2. Universität Karlsruhe, Kaiserstraße 12, 76131 Karlsruhe, Germany;3. Northwestern Center for Atom-Probe Tomography, 2220 Campus Drive, Evanston, IL 60208-3108, USA
Abstract:The age-hardening response at 300 °C of Al–0.06Sc–0.02RE (at.%, with RE = Tb, Ho, Tm or Lu) is found to be similar to that of binary Al–0.08Sc (at.%), except that a shorter incubation period for hardening is observed, which is associated with nanoscale RE-rich Al3(RE1?xScx) precipitates. In addition, Al–0.06Sc–0.02Tb (at.%) has a much lower peak microhardness than that of Al–0.08Sc (at.%) due to the small solubility of Tb in α-Al(Sc). Peak-age hardening occurs after 24 h, and is associated with a high number density of nanoscale Sc-rich Al3(Sc1?xREx) precipitates. Analysis by three-dimensional local-electrode atom-probe tomography shows that x increases with increasing atomic number, and that the REs partition to the core of the precipitates.
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