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BaMgSi_2O_6:RE~(3+)(RE=Tb,Ce)的真空紫外光谱特性
引用本文:唐伟,何大伟,周丹,王永生.BaMgSi_2O_6:RE~(3+)(RE=Tb,Ce)的真空紫外光谱特性[J].稀有金属材料与工程,2009,38(Z2).
作者姓名:唐伟  何大伟  周丹  王永生
作者单位:北京交通大学,发光与光信息技术教育部重点实验室,北京,100044
基金项目:国家自然科学基金,北京市科学技术委员会,国家杰出青年科学基金,北京自然科学基金 
摘    要:研究了MMgSi_2O_6:Tb~(3+) (M=Ca, Sr, Ba)样品的结构、发光特性.MMgSi_2O_6:Tb~(3+) (M=Ca,Sr , Ba)具有硅酸钙镁石结构,基质掺入铽离子后结构没有明显变化.结果表明:MMgSi_2O_6:Tb~(3+) (M=Ca, Sr ,Ba)在168、220和294 nm附近有强烈的吸收峰.在168 nm真空紫外激发下,546 nm是主发射峰.当材料BaMgSi_2O_6:Tb~(3+)中掺杂Ce~(3+)时,BaMgSi_2O_6:Tb~(3+)样品在168 nm真空紫外激发下的发射强度明显下降.

关 键 词:硅酸盐  能量传递  稀土离子

VUV Luminescence Properties of BaMgSi_2O_6:RE~(3+)(RE=Tb,Ce)
Tang Wei,He Dawei,Zhou Dan,Wang Yongsheng.VUV Luminescence Properties of BaMgSi_2O_6:RE~(3+)(RE=Tb,Ce)[J].Rare Metal Materials and Engineering,2009,38(Z2).
Authors:Tang Wei  He Dawei  Zhou Dan  Wang Yongsheng
Affiliation:Tang Wei,He Dawei,Zhou Dan,Wang Yongsheng (Key Laboratory of Luminescence , Optical Information,Ministry of Education,Beijing Jiao Tong University,Beijing 100044,China)
Abstract:The structure,luminescence properties of MMgSi2O6:Tb3+(M=Ca,Sr,Ba) were studied.The samples belong to the structure of calcium magnesium silicate. The crystal structure does not change as Tb3+ ions are doped to the crystal lattice. The excitation spectra of MMgSi2O6:Tb3+(M=Ca,Sr and Ba) show strong absorption in 168,220 and 294 nm. The emission spectras of samples have revealed four intense (492,546,592,624 nm) and sharp emission under 168nm VUV excitation. The chief emission is in 546 nm. When Ce3+ doped i...
Keywords:VUV  silicate phosphor  VUV  energy transfer  rare earth
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