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A study of the oxidation and wear properties of vegetable oils: Soybean oil without additives
Authors:Waleska Castro  Joseph M. Perez  Sevim Z. Erhan  Filomena Caputo
Affiliation:(1) Chemical Engineering Department, The Pennsylvania State University, 6802 Pennsylvania, University Park;(2) Food & Industrial Oil Research Unit, ARS, NCAUR, USDA, 61604 Peoria, Illinois;(3) Petróleos de Venezuela SA (PDVSA), Caracas, Venezuela
Abstract:The use of biodegradable lubricants in diverse applications continues to increase. Vegetable oils (e.g., soybean oil) are the main biodegradable lubricant base stocks used world-wide. However, there are concerns about their oxidative stability and low-temperature performance. Improvements in oxidative stability can be made through chemical or genetic modifications. This work compared the effects of oils with different chemical compositions. Soybean oil, high-oleic soybean oil, and epoxidized soybean oil were compared in laboratory bench tests. The tests conducted include the Penn State sequential four-ball wear test and the Penn State micro-oxidation test. Oxidation products from the micro-oxidation test were analyzed by FTIR and gel permeation chromatography. In this paper, all oils were evaluated neat, without additives.
Keywords:Friction and wear  oxidation  soybean oil  vegetable oils
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